隋美蓉:Improved photoelectrochemical performance by forming a ZnO/ZnS core/shell nanorod array论文

隋美蓉:Improved photoelectrochemical performance by forming a ZnO/ZnS core/shell nanorod array论文

本文主要研究内容

作者隋美蓉,顾修全,时梅林,王永,刘琳琳(2019)在《Improved photoelectrochemical performance by forming a ZnO/ZnS core/shell nanorod array》一文中研究指出:ZnO nanorod arrays(NRAs) were prepared via a facile hydrothermal method for photoelectrochemical(PEC) applications.Then, ZnS thin shell layers were deposited onto them via a facile hydrothermal treatment process for constructing a ZnO/ZnS core/shell structure. It was demonstrated that the PEC activity of a ZnO NRA is enhanced significantly after the surface modification, although there weren’t any obvious changes in the visible-light harvesting efficiency.Both the Nyquist and Mott-Schottky(M-S) plots were employed to reveal the reason, which was attributed to higher electrocatalytic activity of ZnS than that of ZnO and the resulting higher charge transfer efficiency across the solid/liquid interfaces. Finally, a schematic band model was proposed for clarifying the charge carrier transfer mechanism occurred at the interfaces.

Abstract

ZnO nanorod arrays(NRAs) were prepared via a facile hydrothermal method for photoelectrochemical(PEC) applications.Then, ZnS thin shell layers were deposited onto them via a facile hydrothermal treatment process for constructing a ZnO/ZnS core/shell structure. It was demonstrated that the PEC activity of a ZnO NRA is enhanced significantly after the surface modification, although there weren’t any obvious changes in the visible-light harvesting efficiency.Both the Nyquist and Mott-Schottky(M-S) plots were employed to reveal the reason, which was attributed to higher electrocatalytic activity of ZnS than that of ZnO and the resulting higher charge transfer efficiency across the solid/liquid interfaces. Finally, a schematic band model was proposed for clarifying the charge carrier transfer mechanism occurred at the interfaces.

论文参考文献

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  • 论文详细介绍

    论文作者分别是来自Optoelectronics Letters的隋美蓉,顾修全,时梅林,王永,刘琳琳,发表于刊物Optoelectronics Letters2019年04期论文,是一篇关于,Optoelectronics Letters2019年04期论文的文章。本文可供学术参考使用,各位学者可以免费参考阅读下载,文章观点不代表本站观点,资料来自Optoelectronics Letters2019年04期论文网站,若本站收录的文献无意侵犯了您的著作版权,请联系我们删除。

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