本文主要研究内容
作者（2019）在《Ligand controlled structure of cadmium（Ⅱ） metal-organic frameworks for fluorescence sensing of Fe3+ ion and nitroaromatic compounds》一文中研究指出：Three cadmium（II） metal-organic frameworks（MOFs） based on tetracarboxylate ligands, namely[Cd2（TTTA）（DMF）3]·2 DMF（1）,[Cd2（TB）（H2O）4]·3DMF·H2O（2）and [Cd（TEB）0.5].2 DMF.4 H2O（3） have been designed and synthesized. Complex 1 is a 2-dimensional（2 D） 3,4-connected network with 3,4 L13 topology, complex 2 features a 3-dimensional（3D） 3,4-connected tfa topology with a 2-fold interpenetrating structure and complex 3 has a 3D 4-connected dia topology with a 4-fold interpenetrating structure. Interestingly, 2 exhibits permanent pores and selective adsorption of CO2 over CH4. In addition, 2 shows fluorescence sensing of Fe3+ ion and rapid detection of nitroaromatic compounds（NACs） through fluorescence quenching.
Abstract
Three cadmium（II） metal-organic frameworks（MOFs） based on tetracarboxylate ligands, namely[Cd2（TTTA）（DMF）3]·2 DMF（1）,[Cd2（TB）（H2O）4]·3DMF·H2O（2）and [Cd（TEB）0.5].2 DMF.4 H2O（3） have been designed and synthesized. Complex 1 is a 2-dimensional（2 D） 3,4-connected network with 3,4 L13 topology, complex 2 features a 3-dimensional（3D） 3,4-connected tfa topology with a 2-fold interpenetrating structure and complex 3 has a 3D 4-connected dia topology with a 4-fold interpenetrating structure. Interestingly, 2 exhibits permanent pores and selective adsorption of CO2 over CH4. In addition, 2 shows fluorescence sensing of Fe3+ ion and rapid detection of nitroaromatic compounds（NACs） through fluorescence quenching.
论文参考文献
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：Ligand controlled structure of cadmium（Ⅱ） metal-organic frameworks for fluorescence sensing of Fe3+ ion and nitroaromatic compounds论文
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