本文主要研究内容
作者朱梅花,吴屹伟,郭鸿旭(2019)在《Hydrothermal Synthesis of Polyoxovanadate-based MOFs Microsphere as Supercapacitor》一文中研究指出:Polyoxovanadate-based MOFs microsphere electrode material, [Ni2(4,4?-bipyridine)3(H2O)2V4O12]·2.5 H2O, was synthesized through a simple hydrothermal method, and then characterized through FT-IR, XRD and SEM. Electrochemical properties of the sample as supercapacitor electrodes in aqueous electrolyte were developed and studied by cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy techniques. Results showed that a high specific capacitance of 152.36 F g-1 at current density of 1 A g-1 in 2 M KOH electrolyte, and 97.62% retention after 2500 charge-discharge cycles at current density of 4 A g-1, which is promising for applications in supercapacitors.
Abstract
Polyoxovanadate-based MOFs microsphere electrode material, [Ni2(4,4?-bipyridine)3(H2O)2V4O12]·2.5 H2O, was synthesized through a simple hydrothermal method, and then characterized through FT-IR, XRD and SEM. Electrochemical properties of the sample as supercapacitor electrodes in aqueous electrolyte were developed and studied by cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy techniques. Results showed that a high specific capacitance of 152.36 F g-1 at current density of 1 A g-1 in 2 M KOH electrolyte, and 97.62% retention after 2500 charge-discharge cycles at current density of 4 A g-1, which is promising for applications in supercapacitors.
论文参考文献
[1].Effect of activated carbon and electrolyte on properties of supercapacitor[J]. 周邵云,李新海,王志兴,郭华军,彭文杰.  Transactions of Nonferrous Metals Society of China.2007(06)[2].Surface modification by graphene oxide:An efficient strategy to improve the performance of activated carbon based supercapacitors[J]. Weishi Du,Yaokang Lv,Hongliang Lu,Zaihua Chen,Dominic S.Wright,Cheng Zhang.  Chinese Chemical Letters.2017(12)[3].Towards unlocking high-performance of supercapacitors: From layered transition-metal hydroxide electrode to redox electrolyte.[J]. WANG HaoXiang,ZHANG Wei,CHEN Hong,ZHENG WeiTao.  Science China(Technological Sciences).2015(11)[4].Characteristics of Electric Double Layer in Different Aqueous Electrolyte Solutions for Supercapacitors[J]. PAN Qun1,TU Wenmao1,DING Lan2,MI Guomin2 1.School of Resources and Environmental Engineering,Wuhan University of Technology,Wuhan 430070,Hubei,China;2.Dandong Scking Electronic Development Co.,LTD,Dandong 118000,Liaoning,China.  Wuhan University Journal of Natural Sciences.2012(03)[5].Carbon/carbon supercapacitors[J]. Elzbieta Frackowiak,Qamar Abbas,Franois Bguin.  Journal of Energy Chemistry.2013(02)[6].NASICON-structured Na3.1Zr1.95Mg0.05Si2PO12 solid electrolyte for solid-state sodium batteries[J]. Jing Yang,Hong-Li Wan,Zhi-Hua Zhang,Gao-Zhan Liu,Xiao-Xiong Xu,Yong-Sheng Hu,Xia-Yin Yao.  Rare Metals.2018(06)[7].Impedance Studies of Spinel LiMn2O4 Electrode/electrolyte Interfaces[J]. ZHUANG Quan-chao1,2,FAN Xiao-yong2,XU Jin-mei2,WEI Guo-zhen2,DONG Quan-feng2 and SUN Shi-gang2 1. School of Materials Science and Engineering,China University of Mining & Technology,Xuzhou 221116,P. R. China; 2. State Key Laboratory of Physical Chemistry of Solid Surfaces,Department of Chemistry,Xiamen University,Xiamen 361005,P. R. China.  Chemical Research in Chinese Universities.2008(04)[8].Preparation and characteriza-tion of a novel composite mi-croporous polymer electrolyte for Li-ion batteries[J]. CHEN Zuofeng1, JIANG Yanxia1, ZHUANG Quanchao1, DONG Quanfeng1, 2, WANG Ye1 & SUN Shigang1 1. State Key Laboratory for Physical Chemistry of Solid Surfaces, De- partment of Chemistry, Xiamen University, Xiamen 361005, China; 2. Powerlong Battery Research Institute, Xiamen University, Xiamen 361005, China.  Chinese Science Bulletin.2005(14)[9].Fabrication and electrochemical properties study of LiSiPON electrolyte films[J]. 邢光建,申万,杨志民,毛昌辉,杜军.  广东有色金属学报.2005(Z1)[10].Relation between powder size and electrolyte properties in nano YSZ system[J]. Minfang Han, Lijun Huo, Botao Li, and Suping PengSchool of Chemical and Environmental Engineering, China University of Mining and Technology, Beijing 100083, China.  Journal of University of Science and Technology Beijing(English Edition).2005(01)
论文详细介绍
论文作者分别是来自Chinese Journal of Structural Chemistry的朱梅花,吴屹伟,郭鸿旭,发表于刊物Chinese Journal of Structural Chemistry2019年04期论文,是一篇关于,Chinese Journal of Structural Chemistry2019年04期论文的文章。本文可供学术参考使用,各位学者可以免费参考阅读下载,文章观点不代表本站观点,资料来自Chinese Journal of Structural Chemistry2019年04期论文网站,若本站收录的文献无意侵犯了您的著作版权,请联系我们删除。
标签:Chinese Journal of Structural Chemistry2019年04期论文;
朱梅花:Hydrothermal Synthesis of Polyoxovanadate-based MOFs Microsphere as Supercapacitor论文
下载Doc文档