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作者安哲,周天（2019）在《A Heterometallic Cu(Ⅰ)-Sr(Ⅱ) Coordination Polymer Based on Isonicotinic Acid Ligand: Synthesis, Crystal Structure, Luminescence and Photocatalytic Performance for Methylene Blue Degradation》一文中研究指出：Presented here is a new heterometallic Cu（I）-Sr（Ⅱ） coordination polymer, [Cu（3）Sr2（isonic）5Br2（H2O）3]n·n（H2O）（1, Hisonic = isonicotinic acid）, has been synthesized via the hydrothermal reactions of CuBr, Sr（NO3）2 and isonicotinic acid. The crystal structure is of triclinic system, space group P1 with a = 7.111（2）, b = 14.934（4）, c = 18.0255（11） ?, α = 83.137（15）, β = 87.155（15）, γ = 79.75（2）°, V = 1869.4（8） ?3, C30H29Br2Cu（3）N5O14Sr2, Mr = 1209.27, Z = 2, Dc = 2.148 g/cm3, F（000） = 1178, μ = 6.725 mm-1, R = 0.0500 and wR = 0.1008 for 4688 observed reflections（I > 2s（I））. Single-crystal X-ray diffraction analysis revealed that compound 1 features a 3 D heterometallic framework stabilized by bifunctional isonic ligands. In addition, the luminescent and photocatalytic properties of compound 1 were also investigated at room temperature.
Abstract
Presented here is a new heterometallic Cu（I）-Sr（Ⅱ） coordination polymer, [Cu（3）Sr2（isonic）5Br2（H2O）3]n·n（H2O）（1, Hisonic = isonicotinic acid）, has been synthesized via the hydrothermal reactions of CuBr, Sr（NO3）2 and isonicotinic acid. The crystal structure is of triclinic system, space group P1 with a = 7.111（2）, b = 14.934（4）, c = 18.0255（11） ?, α = 83.137（15）, β = 87.155（15）, γ = 79.75（2）°, V = 1869.4（8） ?3, C30H29Br2Cu（3）N5O14Sr2, Mr = 1209.27, Z = 2, Dc = 2.148 g/cm3, F（000） = 1178, μ = 6.725 mm-1, R = 0.0500 and wR = 0.1008 for 4688 observed reflections（I > 2s（I））. Single-crystal X-ray diffraction analysis revealed that compound 1 features a 3 D heterometallic framework stabilized by bifunctional isonic ligands. In addition, the luminescent and photocatalytic properties of compound 1 were also investigated at room temperature.
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论文作者分别是来自Chinese Journal of Structural Chemistry的安哲,周天，发表于刊物Chinese Journal of Structural Chemistry2019年04期论文，是一篇关于,Chinese Journal of Structural Chemistry2019年04期论文的文章。本文可供学术参考使用，各位学者可以免费参考阅读下载，文章观点不代表本站观点，资料来自Chinese Journal of Structural Chemistry2019年04期论文网站，若本站收录的文献无意侵犯了您的著作版权，请联系我们删除。