本文主要研究内容
作者金峰,籍建葶,谢超,王艺朦,贺淑娜,张磊,杨昭荣,严锋,张清明（2019）在《Characterization of structural transitions and lattice dynamics of hybrid organic–inorganic perovskite CH3NH3PbI3》一文中研究指出：By combining temperature-dependent x-ray diffraction（XRD） with temperature-dependent Raman scattering, we have characterized the structural transitions and lattice dynamics of the hybrid organic–inorganic perovskite CH3NH3PbI3.The XRD measurements cover distinct phases between 15 K and 370 K and demonstrate a general positive thermal expansion.Clear anomalies are found around the transition temperatures.The temperature evolution of the lattice constants reveals that the transition at 160 K/330 K is of the first-/second-order type.Raman measurements uncover three strong lowfrequency modes, which can be ascribed to the vibration of the Pb/I atoms.The temperature evolution of the modes clearly catches these transitions at 160 K and 330 K, and confirms the transition types, which are exactly consistent with the XRD results.The present study may set an experimental basis to understand the high conversion efficiency in methylammonium lead iodide.
Abstract
By combining temperature-dependent x-ray diffraction（XRD） with temperature-dependent Raman scattering, we have characterized the structural transitions and lattice dynamics of the hybrid organic–inorganic perovskite CH3NH3PbI3.The XRD measurements cover distinct phases between 15 K and 370 K and demonstrate a general positive thermal expansion.Clear anomalies are found around the transition temperatures.The temperature evolution of the lattice constants reveals that the transition at 160 K/330 K is of the first-/second-order type.Raman measurements uncover three strong lowfrequency modes, which can be ascribed to the vibration of the Pb/I atoms.The temperature evolution of the modes clearly catches these transitions at 160 K and 330 K, and confirms the transition types, which are exactly consistent with the XRD results.The present study may set an experimental basis to understand the high conversion efficiency in methylammonium lead iodide.
论文参考文献
论文详细介绍
论文作者分别是来自Chinese Physics B的金峰,籍建葶,谢超,王艺朦,贺淑娜,张磊,杨昭荣,严锋,张清明，发表于刊物Chinese Physics B2019年07期论文，是一篇关于,Chinese Physics B2019年07期论文的文章。本文可供学术参考使用，各位学者可以免费参考阅读下载，文章观点不代表本站观点，资料来自Chinese Physics B2019年07期论文网站，若本站收录的文献无意侵犯了您的著作版权，请联系我们删除。