:Methane Storage and Synthesis of HKUST-1 Prepared with Different Solvent论文

:Methane Storage and Synthesis of HKUST-1 Prepared with Different Solvent论文

本文主要研究内容

作者(2019)在《Methane Storage and Synthesis of HKUST-1 Prepared with Different Solvent》一文中研究指出:The metal-organic framework HKUST-1 was prepared by different solvents.Several analytical tools such as scanning electron microscope(SEM),X-ray diffraction(XRD),N2 adsorption-desorption have been used to characterize the as-synthesized samples.Meanwhile,the solubility of organic ligands in solvents and the CH, adsorption capacity of samples were also detected.The results showed that HKUST-1 prepared with N,N-dimethylformamide(DMF)used as solvent exhibited excellent CH4 adsorption performance.Further studies have shown that the improved CH4 adsorption properties could be attributed to higher solubility of the ligand 1,3,5-benzenetricarboxylic acid in DMF and larger specific surface areas.This work can provide a novel sight for preparing highly efficient CH4 adsorbent materials by improving the solubility of ligand.

Abstract

The metal-organic framework HKUST-1 was prepared by different solvents.Several analytical tools such as scanning electron microscope(SEM),X-ray diffraction(XRD),N2 adsorption-desorption have been used to characterize the as-synthesized samples.Meanwhile,the solubility of organic ligands in solvents and the CH, adsorption capacity of samples were also detected.The results showed that HKUST-1 prepared with N,N-dimethylformamide(DMF)used as solvent exhibited excellent CH4 adsorption performance.Further studies have shown that the improved CH4 adsorption properties could be attributed to higher solubility of the ligand 1,3,5-benzenetricarboxylic acid in DMF and larger specific surface areas.This work can provide a novel sight for preparing highly efficient CH4 adsorbent materials by improving the solubility of ligand.

论文参考文献

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  • 论文详细介绍

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