韩友:A Capacity Supercapacitor Electrode Material of Ni-MOF with High Surface Area and Porosity论文

韩友:A Capacity Supercapacitor Electrode Material of Ni-MOF with High Surface Area and Porosity论文

本文主要研究内容

作者韩友,侯向阳,王潇,付峰,唐龙,王记江(2019)在《A Capacity Supercapacitor Electrode Material of Ni-MOF with High Surface Area and Porosity》一文中研究指出:Materials with high surface area, tailored pore size and good electrical conductivity are needed for improved supercapacitors(SCs). Metal-organic frameworks(MOFs) have high surface areas and tailored pore sizes. Here, the MOF(1) of [Ni3(μ3 OH)(pba)3(bpdc)1.5]·11.5 DMA· 0.5 CH3 OH·7 H2O is good enough to result in electrode materials with nearly ideal supercapacitive behavior at the rate up to 50 mV?s-1 in a KOH electrolyte. The super capacitive performance of MOF(1) was measured using cyclic voltammogram, galvanostatic discharge and electrochemical impedance spectroscopy measurements. This MOF(1) as electrode exhibits the highest super capacitive properties with 417 F?g-1, the maximum storage energy and power density are 9.27 and 2.38 kW?kg-1. The long term stability of MOF(1) as SCs is checked that the capacitance is decreased by 17% after 1000 cycles.

Abstract

Materials with high surface area, tailored pore size and good electrical conductivity are needed for improved supercapacitors(SCs). Metal-organic frameworks(MOFs) have high surface areas and tailored pore sizes. Here, the MOF(1) of [Ni3(μ3 OH)(pba)3(bpdc)1.5]·11.5 DMA· 0.5 CH3 OH·7 H2O is good enough to result in electrode materials with nearly ideal supercapacitive behavior at the rate up to 50 mV?s-1 in a KOH electrolyte. The super capacitive performance of MOF(1) was measured using cyclic voltammogram, galvanostatic discharge and electrochemical impedance spectroscopy measurements. This MOF(1) as electrode exhibits the highest super capacitive properties with 417 F?g-1, the maximum storage energy and power density are 9.27 and 2.38 kW?kg-1. The long term stability of MOF(1) as SCs is checked that the capacitance is decreased by 17% after 1000 cycles.

论文参考文献

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  • 论文详细介绍

    论文作者分别是来自Chinese Journal of Structural Chemistry的韩友,侯向阳,王潇,付峰,唐龙,王记江,发表于刊物Chinese Journal of Structural Chemistry2019年10期论文,是一篇关于,Chinese Journal of Structural Chemistry2019年10期论文的文章。本文可供学术参考使用,各位学者可以免费参考阅读下载,文章观点不代表本站观点,资料来自Chinese Journal of Structural Chemistry2019年10期论文网站,若本站收录的文献无意侵犯了您的著作版权,请联系我们删除。

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    韩友:A Capacity Supercapacitor Electrode Material of Ni-MOF with High Surface Area and Porosity论文
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