：Synthesized high-silica hierarchical porous ZSM-5 and optimization of its reaction conditions in benzene alkylation with methanol论文

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作者（2019）在《Synthesized high-silica hierarchical porous ZSM-5 and optimization of its reaction conditions in benzene alkylation with methanol》一文中研究指出：In our present work, the high-silica hierarchical porous ZSM-5 with appropriate Br（o|¨）nsted acidity and hierarchical porous structure was synthesized by sol-gel method for continuously catalytic conversion of benzene alkylation with methanol to xylene. The effects of temperature, pressure, benzene/methanol molar ratio and weight hour space velocity（WHSV） on the catalytic performance of the catalyst were investigated as well. As a result, the high-silica hierarchical porous ZSM-5 showed great performance as the yield of xylene was up to 41.1% under the optimum reaction conditions(500 ℃,0.1 MPa,Mbenzene/Mmethanol= 1:1.5 and WHSV=4 h 1), while the selectivity to by-product, ethylbenzene, was well suppressed（below 0.1%）. In addition, the catalyst structure and properties were characterized by the means of XRD, IR, TPD,SEM, TEM and N2 physical adsorption technologies.

Abstract

In our present work, the high-silica hierarchical porous ZSM-5 with appropriate Br（o|¨）nsted acidity and hierarchical porous structure was synthesized by sol-gel method for continuously catalytic conversion of benzene alkylation with methanol to xylene. The effects of temperature, pressure, benzene/methanol molar ratio and weight hour space velocity（WHSV） on the catalytic performance of the catalyst were investigated as well. As a result, the high-silica hierarchical porous ZSM-5 showed great performance as the yield of xylene was up to 41.1% under the optimum reaction conditions(500 ℃,0.1 MPa,Mbenzene/Mmethanol= 1:1.5 and WHSV=4 h 1), while the selectivity to by-product, ethylbenzene, was well suppressed（below 0.1%）. In addition, the catalyst structure and properties were characterized by the means of XRD, IR, TPD,SEM, TEM and N2 physical adsorption technologies.

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