:A Theoretical Study on Transitional Shear Flow Behavior of the Compressible and Isothermal Thermoplastic Polymer简论文

:A Theoretical Study on Transitional Shear Flow Behavior of the Compressible and Isothermal Thermoplastic Polymer简论文

本文主要研究内容

作者(2019)在《A Theoretical Study on Transitional Shear Flow Behavior of the Compressible and Isothermal Thermoplastic Polymer简》一文中研究指出:By extending the virtual conformational element of the polymer chain, a dynamic end-to-end(ETE) vector was presented to describe the chain’s instantaneous morphology based on the spring-bead theory. A feasible viscoelastic model was proposed to describe the rheological behavior of the isothermal thermoplastic polymer materials, based on the molecular kinetics, thermodynamics, and continuum mechanics method. The model is simplified as the generalized Newton’s law. Its integral formula with similar form to the KBKZ model was also derived. Rheological experiments were carried out with the isotactic polypropylene material. The experimental results reveal that the viscoelastic model exhibits a three-stage rheological characteristic. There is a distinct high-elastic rheological region in the middle stage, reflecting the pseudoplastic fluids properties. Compared with the Ostwald-de Waele power law model, the viscoelastic model shows a better agreement with the rheological practices.

Abstract

By extending the virtual conformational element of the polymer chain, a dynamic end-to-end(ETE) vector was presented to describe the chain’s instantaneous morphology based on the spring-bead theory. A feasible viscoelastic model was proposed to describe the rheological behavior of the isothermal thermoplastic polymer materials, based on the molecular kinetics, thermodynamics, and continuum mechanics method. The model is simplified as the generalized Newton’s law. Its integral formula with similar form to the KBKZ model was also derived. Rheological experiments were carried out with the isotactic polypropylene material. The experimental results reveal that the viscoelastic model exhibits a three-stage rheological characteristic. There is a distinct high-elastic rheological region in the middle stage, reflecting the pseudoplastic fluids properties. Compared with the Ostwald-de Waele power law model, the viscoelastic model shows a better agreement with the rheological practices.

论文参考文献

  • [1].Correlation between rheological behavior and structure of multi-component polymer systems[J]. ZUO Min1,2 ZHENG Qiang1 1 Key Laboratory of Macromolecular Synthesis and Functionalization, Ministry of Education, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China; 2 Department of Chemical Engineering, Hong Kong University of Science and Technology, Clear Bay, Kowloon, Hong Kong.  Science in China(Series B:Chemistry).2008(01)
  • [2].Application in metal rheological forming of element-free Galerkin method[J]. 罗迎社,殷水平,余敏.  Journal of Central South University of Technology.2008(S1)
  • [3].Couple analysis on strength reduction theory and rheological mechanism for slope stability[J]. 刘子振,言志信,段建.  Journal of Central South University of Technology.2008(S1)
  • [4].Research on rheological properties of micro-fine grouting cement[J]. 管学茂,王雨利,杨雷.  Journal of Coal Science & Engineering(China).2003(01)
  • [5].Thermal-rheological structure of the lithosphere beneath two types of basins in eastern and western China[J]. 王良书,李成,刘福田,李华,卢华复,刘绍文.  Science in China(Series D:Earth Sciences).2000(S1)
  • [6].A new general rheological model for rheological lubrication[J]. 张鹏顺,曲全利,黄浩.  Journal of Harbin Institute of Technology.1999(03)
  • [7].Dislocation evolution with rheological forming of metal[J]. Luo Yingshe(罗迎社) 1, Guo Xiaogang(郭小刚) 1, Mei Yafu(梅亚夫) 2, Hu Yungui(胡云贵) 3 1. Research Institute of Fundamental Mechanics and Materials Engineering, 2. College of Mechanical Engineering, Xiangtan University, Xiangtan 411105, P. R. China.  Transactions of Nonferrous Metals Society of China.1999(03)
  • [8].STUDY ON RHEOLOGICAL BEHAVIOR OF THE MELTED POLYMER——RELATIONSHIP BETWEEN η_α AND _n[J]. 常棉,张希庆,曹永华,王梓杰,王少君.  Science Bulletin.1988(10)
  • [9].Effects of stress conditions on rheological properties of granular soil in large triaxial rheology laboratory tests[J]. 陈晓斌,张家生,刘宝琛,唐孟雄.  Journal of Central South University of Technology.2008(S1)
  • [10].Traction rheological properties of simulative soil for deep-sea sediment[J]. QI Cailing,RAO Qiuhua,LIU Qi,MA Wenbo.  Journal of Oceanology and Limnology.2019(01)
  • 论文详细介绍

    论文作者分别是来自Chinese Journal of Polymer Science的,发表于刊物Chinese Journal of Polymer Science2019年05期论文,是一篇关于,Chinese Journal of Polymer Science2019年05期论文的文章。本文可供学术参考使用,各位学者可以免费参考阅读下载,文章观点不代表本站观点,资料来自Chinese Journal of Polymer Science2019年05期论文网站,若本站收录的文献无意侵犯了您的著作版权,请联系我们删除。

    标签:;  

    :A Theoretical Study on Transitional Shear Flow Behavior of the Compressible and Isothermal Thermoplastic Polymer简论文
    下载Doc文档

    猜你喜欢