:Electrocatalytic activity of LaSr3Fe3O10 and LaSr3Fe3O10-GO towards oxygen reduction reaction in alkaline medium论文

:Electrocatalytic activity of LaSr3Fe3O10 and LaSr3Fe3O10-GO towards oxygen reduction reaction in alkaline medium论文

本文主要研究内容

作者(2019)在《Electrocatalytic activity of LaSr3Fe3O10 and LaSr3Fe3O10-GO towards oxygen reduction reaction in alkaline medium》一文中研究指出:Oxygen reduction reaction(ORR) plays a critical role in many energy conversion and storage processes.Therein, a comparative study of the electrocatalytic activity for ORR in 0.1 mol/L KOH solution was conducted using layered perovskite-like LaSr3Fe3O10 and LaSr3 Fe3O10-graphene oxide(GO) composite as electrodes. Linear sweep voltammetry(LSV) results show that the LaSr3 Fe3O10-GO hybrid exhibits higher current density, a more positive onset potential(-0.15 V vs. Hg/HgO) in comparison with LaSr3Fe3O10.The value of the overall transferred electrons for both catalysts implies a dominant two electron process for ORR. Both catalysts under alkalic conditions exhibit a two-step Tafel slope, suggesting a change in the reaction mechanism for ORR. The composite electrode exhibits a higher ORR current density, but inferior durability performances in relative to the LaSr3Fe3O10electrode.

Abstract

Oxygen reduction reaction(ORR) plays a critical role in many energy conversion and storage processes.Therein, a comparative study of the electrocatalytic activity for ORR in 0.1 mol/L KOH solution was conducted using layered perovskite-like LaSr3Fe3O10 and LaSr3 Fe3O10-graphene oxide(GO) composite as electrodes. Linear sweep voltammetry(LSV) results show that the LaSr3 Fe3O10-GO hybrid exhibits higher current density, a more positive onset potential(-0.15 V vs. Hg/HgO) in comparison with LaSr3Fe3O10.The value of the overall transferred electrons for both catalysts implies a dominant two electron process for ORR. Both catalysts under alkalic conditions exhibit a two-step Tafel slope, suggesting a change in the reaction mechanism for ORR. The composite electrode exhibits a higher ORR current density, but inferior durability performances in relative to the LaSr3Fe3O10electrode.

论文参考文献

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