本文主要研究内容
作者张通,龙丽娟,何文涛,何敏,秦舒浩,于杰（2019）在《9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物衍生物阻燃聚乳酸的性能研究》一文中研究指出：通过甲醛与9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物(DOPO)反应合成出含羟基的DOPO衍生物9,10-二氢-9-氧杂-10-磷杂菲-10-甲醇10-氧化物(ODOPM).采用傅里叶变换红外光谱(FTIR),核磁共振谱(1HNMR,31P-NMR)以及质谱分析(MS)确定了其结构,同时研究了ODOPM对聚乳酸(PLA)阻燃性能与热性能的影响,并与10-(2,5-二羟基苯基)-10H-9-氧杂-10-磷杂菲-10-氧化物(DOPO-HQ)进行了比较.通过热重分析(TG)、氧指数(LOI)、垂直燃烧(UL-94)和锥形量热(CCT)等研究了2种阻燃剂对PLA阻燃性能及热降解行为的影响,发现2种阻燃剂都能降低材料的热释放峰值(PHRR),提高复合材料的热稳定性和残炭量,然而PLA/ODOPM相对于PLA/DOPO-HQ具有更高的氧指数和燃烧等级. PLA加入5%的ODOPM时就能达到V-0级,加入15%时,氧指数能达到34.4%,而DOPO-HQ加入量为15%时才能达到V-0,LOI值也仅仅28.8%.扫描电镜和拉曼对炭层的分析表明DOPO-HQ复合材料能够形成更加完整致密的炭层,因此具有更好的固相阻燃作用,此外TG-FTIR表明2种阻燃剂都能起到气相阻燃作用. X射线能量色谱(EDS)发现2种复合材料炭层中具有较高的P含量,这可能是炭层中形成了大量的聚磷酸酯.最后流变分析表明ODOPM会降低PLA的复数黏度,且PLA/ODOPM黏度远低于PLA/DOPO-HQ.
Abstract
tong guo jia quan yu 9,10-er qing -9-yang za -10-lin za fei -10-yang hua wu (DOPO)fan ying ge cheng chu han qiang ji de DOPOyan sheng wu 9,10-er qing -9-yang za -10-lin za fei -10-jia chun 10-yang hua wu (ODOPM).cai yong fu li xie bian huan gong wai guang pu (FTIR),he ci gong zhen pu (1HNMR,31P-NMR)yi ji zhi pu fen xi (MS)que ding le ji jie gou ,tong shi yan jiu le ODOPMdui ju ru suan (PLA)zu ran xing neng yu re xing neng de ying xiang ,bing yu 10-(2,5-er qiang ji ben ji )-10H-9-yang za -10-lin za fei -10-yang hua wu (DOPO-HQ)jin hang le bi jiao .tong guo re chong fen xi (TG)、yang zhi shu (LOI)、chui zhi ran shao (UL-94)he zhui xing liang re (CCT)deng yan jiu le 2chong zu ran ji dui PLAzu ran xing neng ji re jiang jie hang wei de ying xiang ,fa xian 2chong zu ran ji dou neng jiang di cai liao de re shi fang feng zhi (PHRR),di gao fu ge cai liao de re wen ding xing he can tan liang ,ran er PLA/ODOPMxiang dui yu PLA/DOPO-HQju you geng gao de yang zhi shu he ran shao deng ji . PLAjia ru 5%de ODOPMshi jiu neng da dao V-0ji ,jia ru 15%shi ,yang zhi shu neng da dao 34.4%,er DOPO-HQjia ru liang wei 15%shi cai neng da dao V-0,LOIzhi ye jin jin 28.8%.sao miao dian jing he la man dui tan ceng de fen xi biao ming DOPO-HQfu ge cai liao neng gou xing cheng geng jia wan zheng zhi mi de tan ceng ,yin ci ju you geng hao de gu xiang zu ran zuo yong ,ci wai TG-FTIRbiao ming 2chong zu ran ji dou neng qi dao qi xiang zu ran zuo yong . Xshe xian neng liang se pu (EDS)fa xian 2chong fu ge cai liao tan ceng zhong ju you jiao gao de Phan liang ,zhe ke neng shi tan ceng zhong xing cheng le da liang de ju lin suan zhi .zui hou liu bian fen xi biao ming ODOPMhui jiang di PLAde fu shu nian du ,ju PLA/ODOPMnian du yuan di yu PLA/DOPO-HQ.
论文参考文献
论文详细介绍
论文作者分别是来自高分子学报的张通,龙丽娟,何文涛,何敏,秦舒浩,于杰，发表于刊物高分子学报2019年01期论文，是一篇关于阻燃论文,聚乳酸论文,二氢氧杂磷杂菲甲醇氧化物论文,高分子学报2019年01期论文的文章。本文可供学术参考使用，各位学者可以免费参考阅读下载，文章观点不代表本站观点，资料来自高分子学报2019年01期论文网站，若本站收录的文献无意侵犯了您的著作版权，请联系我们删除。
标签：阻燃论文; 聚乳酸论文; 二氢氧杂磷杂菲甲醇氧化物论文; 高分子学报2019年01期论文;