：Bifunctional metal–organic frameworks toward photocatalytic CO2reduction by post-synthetic ligand exchange论文

本文主要研究内容

作者（2019）在《Bifunctional metal–organic frameworks toward photocatalytic CO2reduction by post-synthetic ligand exchange》一文中研究指出：Photocatalytic reduction of CO2 to useful fuel has been identified as a promising strategy to address the energy and environmental issues. Development of welldefined photocatalysts toward CO2 reduction has attracted increasing interest to gain insight into the reactive mechanism. Herein, by post-synthetic ligand exchange, a bifunctional Re-based metal–organic framework（MOF）was successfully prepared. It not only serves as a photosensitizer but also acts as a catalyst for photochemical reduction of CO2. Furthermore, it is found that a Re-based MOF containing 30% Re-based ligands displays improved activity compared to MOF with 100% Re-based ligands.This work provides clues to the design and synthesis of bifunctional MOFs toward photocatalytic CO2reduction.

Abstract

Photocatalytic reduction of CO2 to useful fuel has been identified as a promising strategy to address the energy and environmental issues. Development of welldefined photocatalysts toward CO2 reduction has attracted increasing interest to gain insight into the reactive mechanism. Herein, by post-synthetic ligand exchange, a bifunctional Re-based metal–organic framework（MOF）was successfully prepared. It not only serves as a photosensitizer but also acts as a catalyst for photochemical reduction of CO2. Furthermore, it is found that a Re-based MOF containing 30% Re-based ligands displays improved activity compared to MOF with 100% Re-based ligands.This work provides clues to the design and synthesis of bifunctional MOFs toward photocatalytic CO2reduction.

论文参考文献

论文详细介绍

论文作者分别是来自Rare Metals的，发表于刊物Rare Metals2019年05期论文，是一篇关于,Rare Metals2019年05期论文的文章。本文可供学术参考使用，各位学者可以免费参考阅读下载，文章观点不代表本站观点，资料来自Rare Metals2019年05期论文网站，若本站收录的文献无意侵犯了您的著作版权，请联系我们删除。

标签：Rare Metals2019年05期论文;