陈昆:黄铁矿强化零价铁去除Orange Ⅱ研究论文

陈昆:黄铁矿强化零价铁去除Orange Ⅱ研究论文

本文主要研究内容

作者陈昆,李益民(2019)在《黄铁矿强化零价铁去除Orange Ⅱ研究》一文中研究指出:零价铁(ZVI)具有价廉易得、安全无毒、还原性较强等特点,能用于去除环境中众多污染物.但其反应活性会随着介质pH值的升高、表面钝化产物的形成而降低,而且反应介质的pH值适用范围较窄.将价廉的黄铁矿(pyrite)与零价铁混合,用于处理合成废水中的偶氮染料Orange Ⅱ,研究了介质的pH值、pyrite/ZVI质量比对Orange Ⅱ去除率的影响,并对协同反应机理进行了初步探讨.结果表明:在相同实验条件下,pyrite协同ZVI对Orange Ⅱ的去除率远高于相同剂量pyrite和ZVI分别对Orange Ⅱ去除率的加和.当初始pH=7.0、pyrite/ZVI质量比为1~4时,与Orange Ⅱ反应的表观速率常数是相应零价铁的9.36~28.0倍.此外,在初始pH值为5.0~10.0时,pyrite/ZVI对Orange Ⅱ均显示了良好的去除效果.机理研究表明:在零价铁去除Orange Ⅱ时,pyrite的存在导致了反应介质pH值的降低,并能将ZVI表面钝化产物转化为高还原活性Fe(Ⅱ),从而显示出显著的强化作用.

Abstract

ling jia tie (ZVI)ju you jia lian yi de 、an quan mo du 、hai yuan xing jiao jiang deng te dian ,neng yong yu qu chu huan jing zhong zhong duo wu ran wu .dan ji fan ying huo xing hui sui zhao jie zhi pHzhi de sheng gao 、biao mian dun hua chan wu de xing cheng er jiang di ,er ju fan ying jie zhi de pHzhi kuo yong fan wei jiao zhai .jiang jia lian de huang tie kuang (pyrite)yu ling jia tie hun ge ,yong yu chu li ge cheng fei shui zhong de ou dan ran liao Orange Ⅱ,yan jiu le jie zhi de pHzhi 、pyrite/ZVIzhi liang bi dui Orange Ⅱqu chu lv de ying xiang ,bing dui xie tong fan ying ji li jin hang le chu bu tan tao .jie guo biao ming :zai xiang tong shi yan tiao jian xia ,pyritexie tong ZVIdui Orange Ⅱde qu chu lv yuan gao yu xiang tong ji liang pyritehe ZVIfen bie dui Orange Ⅱqu chu lv de jia he .dang chu shi pH=7.0、pyrite/ZVIzhi liang bi wei 1~4shi ,yu Orange Ⅱfan ying de biao guan su lv chang shu shi xiang ying ling jia tie de 9.36~28.0bei .ci wai ,zai chu shi pHzhi wei 5.0~10.0shi ,pyrite/ZVIdui Orange Ⅱjun xian shi le liang hao de qu chu xiao guo .ji li yan jiu biao ming :zai ling jia tie qu chu Orange Ⅱshi ,pyritede cun zai dao zhi le fan ying jie zhi pHzhi de jiang di ,bing neng jiang ZVIbiao mian dun hua chan wu zhuai hua wei gao hai yuan huo xing Fe(Ⅱ),cong er xian shi chu xian zhe de jiang hua zuo yong .

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  • 论文详细介绍

    论文作者分别是来自绍兴文理学院学报(自然科学)的陈昆,李益民,发表于刊物绍兴文理学院学报(自然科学)2019年01期论文,是一篇关于黄铁矿论文,零价铁论文,协同作用论文,绍兴文理学院学报(自然科学)2019年01期论文的文章。本文可供学术参考使用,各位学者可以免费参考阅读下载,文章观点不代表本站观点,资料来自绍兴文理学院学报(自然科学)2019年01期论文网站,若本站收录的文献无意侵犯了您的著作版权,请联系我们删除。

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    陈昆:黄铁矿强化零价铁去除Orange Ⅱ研究论文
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