本文主要研究内容
作者（2019）在《Recovering REEs from NdFeB wastes with high purity and efficiency by leaching and selective precipitation process with modified agents》一文中研究指出：A leaching and selective precipitation approach is proposed in this work to recover rare earth elements(REEs) from NdFeB magnet wastes collected from industry. Hydrochloric acid and oxalic acid were employed as the leaching and precipitation agents, respectively. Hexamethylenetetramine(HMTA) or tartaric acid was used as the chelating agent during leaching. Both leaching and precipitation processes were optimized individually. For leaching process, the effects of two different chelating agents, the concentrations of leaching agent, chelating agent, and temperature on the extraction and recovery yields were investigated. The optimized process based on the factorial experiment was determined to be the hydrochloric acid concentration of 6 mol/L, the tartaric acid concentration of 50 g/L, and the temperature of 313 K, by which the extraction yields of Fe and REEs up to 67.99% and 99.27%, respectively, are obtained. For the precipitation process, the optimized oxalic acid dosage and pH value were also determined. The produced RE oxide products have the purity and recovery yield up to 95.83% and 90.18%,respectively. These results indicate that the present method with low acid consumption and high product purity has advantages over many other approaches for REE recovery.
Abstract
A leaching and selective precipitation approach is proposed in this work to recover rare earth elements(REEs) from NdFeB magnet wastes collected from industry. Hydrochloric acid and oxalic acid were employed as the leaching and precipitation agents, respectively. Hexamethylenetetramine(HMTA) or tartaric acid was used as the chelating agent during leaching. Both leaching and precipitation processes were optimized individually. For leaching process, the effects of two different chelating agents, the concentrations of leaching agent, chelating agent, and temperature on the extraction and recovery yields were investigated. The optimized process based on the factorial experiment was determined to be the hydrochloric acid concentration of 6 mol/L, the tartaric acid concentration of 50 g/L, and the temperature of 313 K, by which the extraction yields of Fe and REEs up to 67.99% and 99.27%, respectively, are obtained. For the precipitation process, the optimized oxalic acid dosage and pH value were also determined. The produced RE oxide products have the purity and recovery yield up to 95.83% and 90.18%,respectively. These results indicate that the present method with low acid consumption and high product purity has advantages over many other approaches for REE recovery.
论文参考文献
论文详细介绍
论文作者分别是来自Journal of Rare Earths的，发表于刊物Journal of Rare Earths2019年02期论文，是一篇关于,Journal of Rare Earths2019年02期论文的文章。本文可供学术参考使用，各位学者可以免费参考阅读下载，文章观点不代表本站观点，资料来自Journal of Rare Earths2019年02期论文网站，若本站收录的文献无意侵犯了您的著作版权，请联系我们删除。