：Rational design of carbon-based metal-free catalysts for electrochemical carbon dioxide reduction: A review论文

本文主要研究内容

作者（2019）在《Rational design of carbon-based metal-free catalysts for electrochemical carbon dioxide reduction: A review》一文中研究指出：Electrochemical CO2 reduction to chemicals or fuels presents one of the most promising strategies for managing the global carbon balance, which yet poses a significant challenge due to lack of efficient and durable electrocatalyst as well as the understanding of the CO2 reduction reaction（CO2RR） mechanism.Benefiting from the large surface area, high electrical conductivity, and tunable structure, carbon-based metal-free materials（CMs） have been extensively studied as cost-effective electrocatalysts for CO2RR.The development of CMs with low cost, high activity and durability for CO2RR has been considered as one of the most active and competitive directions in electrochemistry and material science.In this review article,some up-to-date strategies in improving the CO2RR performance on CMs are summarized.Specifically, the approaches to optimize the adsorption of CO2RR intermediates, such as tuning the physical and electronic structure are introduced, which can enhance the electrocatalytic activity of CMs effectively.Finally, some design strategies are proposed to prepare CMs with high activity and selectivity for CO2RR.

Abstract

Electrochemical CO2 reduction to chemicals or fuels presents one of the most promising strategies for managing the global carbon balance, which yet poses a significant challenge due to lack of efficient and durable electrocatalyst as well as the understanding of the CO2 reduction reaction（CO2RR） mechanism.Benefiting from the large surface area, high electrical conductivity, and tunable structure, carbon-based metal-free materials（CMs） have been extensively studied as cost-effective electrocatalysts for CO2RR.The development of CMs with low cost, high activity and durability for CO2RR has been considered as one of the most active and competitive directions in electrochemistry and material science.In this review article,some up-to-date strategies in improving the CO2RR performance on CMs are summarized.Specifically, the approaches to optimize the adsorption of CO2RR intermediates, such as tuning the physical and electronic structure are introduced, which can enhance the electrocatalytic activity of CMs effectively.Finally, some design strategies are proposed to prepare CMs with high activity and selectivity for CO2RR.

论文参考文献

论文详细介绍

论文作者分别是来自Journal of Energy Chemistry的，发表于刊物Journal of Energy Chemistry2019年09期论文，是一篇关于,Journal of Energy Chemistry2019年09期论文的文章。本文可供学术参考使用，各位学者可以免费参考阅读下载，文章观点不代表本站观点，资料来自Journal of Energy Chemistry2019年09期论文网站，若本站收录的文献无意侵犯了您的著作版权，请联系我们删除。

标签：Journal of Energy Chemistry2019年09期论文;